Table 2 Substrate scope for nickel-catalyzed reductive aryl-thiolation and selenylation

From: Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides

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  1. Reaction conditions: alkyl bromides 1 (1.0 equiv.); benzenesulfonothioates 2 (1.1 equiv.); Ni(PPh3)2Cl2 (5.0 mol%); L2 (7.5 mol%); Mn (1.5 equiv.); DMF (0.2 M); N2 atmosphere; 30 °C; 5 h. Yields of isolated products are given
  2. †L2 (12.5 mol%), 12 h
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