Table 2 Kinetic analysis of Pd/H-MOR and Pd/Na-MOR
From: Stable complete methane oxidation over palladium based zeolite catalysts
Sample | Reaction orders (CH4/O2/H2O) | Eact, kJ/mol (0/5 vol% H2O) | T50, °C (0/5 vol% H2O) | TOFa, s−1 (275 °C, 0% H2O) | TOFa, s−1 (340 °C, 5% H2O) |
|---|---|---|---|---|---|
Pd/H-MOR | 0.9/0.1/−1.0 | 84/155 | 395/435 | 0.003 | 0.002 |
Pd/Na-MOR | 1.0/0.1/−1.1 | 75/158 | 335/375 | 0.013 | 0.014 |
