Fig. 5
From: Self-assembly of metal–organic polyhedra into supramolecular polymers with intrinsic microporosity
Drying of supramolecular colloidal gel leading to a supramolecular aerogel, and effect on gas sorption properties of the macroscopic structures of the polymers. a Photographs of a standalone SCG-1 (a) and b, the corresponding SAG-1; scale bars: 1 cm. c Representative FESEM image of SAG-1 and a magnified view of the material; scale bars: 1 µm, and (inset) 200 nm. d CO2 adsorption isotherm at 195 K and e N2 adsorption isotherm at 77 K of SAG-1 (red), CPP-1_small (blue), CPP-1_big (green), and C12RhMOP (black). The inset highlights the adsorption at low pressure. Filled and empty symbols correspond to adsorption and desorption, respectively
