Table 2 Summary of the textural characteristics of a permanent porous glass derived from ZIF-76-mbIm

From: Metal-organic framework glasses with permanent accessible porosity

 

ZIF-76-mbIm

agZIF-76-mbIm

Uptake of CO2 (1 bar, 273 K)

10.0 wt%

7.0 wt%

Surface area from N2 / 77 K dataa

1173

d

Surface area from CO2/273 K dataa

643

375

Pore volume from N2/77 K datab

0.50

d

Pore volume from CO2/273 K datab

0.17

0.12

Isosteric heat of adsorption, Qst (CO2)c

−26.3

−29.3

  1. aIn cm2 g–1 using the BET model (N2) or NLDFT fitting (CO2)
  2. bVolume accessible to adsorbate in cm3 g–1 at 1  bar using the density of liquid adsorbate (N2) or NLDFT fitting
  3. cIn kJ mol–1 at zero loading
  4. dNot measurable due to diffusion limitations