Fig. 3
From: Irradiation-induced palladium-catalyzed decarboxylative desaturation enabled by a dual ligand system
Scope of the reaction with respect to α-hydroxy and α-amino carboxylates. Reaction conditions: redox-active esters (0.2 mmol), PdCl2 (5 mol%), Xantphos (6 mol%), Cy-JohnPhos (10 mol%), and 2,4,6-collidine (1.0 equiv) in DMA (2 mL), irradiated with 30 W blue LEDs for 15 h under Ar. Yields of isolated products, the ratio of isomers determined by 1H NMR analysis
