Table 2 Peak positions in the FT-IR spectra and their corresponding vibrational modes

From: Earthquake lubrication and healing explained by amorphous nanosilica

Vibrational mode

Position of peak (cm−1)

 

Nanosilica

Commercial nanosilica (this study)

Wear material (this study)

Powdered novaculite (this study)

α-quartz

Isolated (free) silanol66

3747

3745

   

H-bonded silanol66

3660

3650

   

Stretching of H2O66

3450

3348

3424

  

Asymmetric stretching of Si–O–Si20

1089

1066

1052

1087, 1043

1175, 1100

Bending of Si–OH67

972

1066

   

Symmetric stretching of Si–O–Si20,68

812

798

797, 780 (double peak)

795, 776 (double peak)

797, 778 (double peak)

Symmetric bending of Si–O–Si20

  

695

694

695

Asymmetric bending of O–Si–O20

474

539 (shoulder), 452

515 (shoulder), 447

510 (shoulder), 446

516 (shoulder), 470