Fig. 4 | Nature Communications

Fig. 4

From: Asymmetric catalysis mediated by a mirror symmetry-broken helical nanoribbon

Fig. 4

Chiral environment of the cation-binding sites in PBTABA nanoribbons. a Schematic representation of the binding of methylene blue (MB) onto PBTABA at its carboxylate units via an electrostatic interaction. b, c Circular dichroism (CD, b) and circularly polarized luminescence (CPL, λext = 290 nm, c) spectra at 25 °C of DMF/water (7/3, v/v; 1 mL) suspensions of (−)-PBTABA (blue) and (+)-PBTABA (pink) ([BTABA] = 5.3 mM, Fig. 2d, e). d, e CD (d) and CPL (λext = 550 nm, e) spectra at 25 °C of DMF/water (7/3, v/v; 1 mL) suspensions of (−)-PBTABA (blue) and (+)-PBTABA (pink) ([BTABA] = 5.3 mM) containing MB ([MB]/[BTABA] = 20%). Source data are provided as a Source Data file

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