Table 1 Electrochemical anodic glucose oxidation and OER in 1 M KOH.
From: Efficient electrochemical production of glucaric acid and H2 via glucose electrolysis
Entry | Catalyst | Cglucose (mM) | J (mA cm−2) (E = 1.30 V) | TOF (s−1) (E = 1.30 V) | Potential applied (V) | Reaction time (h) | Glucose conversion (%) | Y (GNA) (%) | Y(GRA) (%) | Y(GNA+GRA) (%) | FE (%) |
|---|---|---|---|---|---|---|---|---|---|---|---|
1 | NiFeOx-NF | 0 | 2.61 | 1.6 × 10−3 | — | — | — | — | — | — | — |
2 | NiFeNx-NF | 0 | 0.90 | 4.7 × 10−3 | — | — | — | — | — | — | — |
3 | NiFeOx-NF | 10 | 17.7 | 0.03 | 1.30 | 2 | 98.3 | 8.6 | 83.3 | 91.9 | 87 |
4 | NiFeOx-NF | 50 | 61.5 | 0.11 | 1.30 | 10 | 93.1 | 11.2 | 75.3 | 86.5 | 79 |
5 | NiFeOx-NF | 100 | 87.6 | 0.16 | 1.30 | 18 | 90.6 | 12.6 | 71.2 | 83.8 | 73 |
6 | NiFeNx-NF | 100 | 22.1 | 0.04 | 1.30 | 18 | 92.7 | 19.6 | 63.8 | 83.4 | 68 |
7 | NiFe(OH)x-NF | 100 | 79.2 | 0.09 | 1.30 | 18 | 88.6 | 21.3 | 56.9 | 78.2 | 64 |
8 | NF | 100 | 20.3 | 1.7 × 10−3 | 1.30 | 18 | 59.2 | 37.3 | 17.2 | 54.5 | 67 |
9 | Pt-C//NF | 100 | 49.3 | 0.04 | 1.30 | 18 | 67.3 | 41.9 | 20.2 | 62.2 | 71 |
10 | RuO2//NF | 100 | 83.8 | 9.4 × 10−3 | 1.30 | 18 | 90.1 | 52.2 | 27.7 | 79.9 | 77 |
