Fig. 3: Driving force dependent sub-picosecond HT in polymer:m-ITIC blends. | Nature Communications

Fig. 3: Driving force dependent sub-picosecond HT in polymer:m-ITIC blends.

From: Sub-picosecond charge-transfer at near-zero driving force in polymer:non-fullerene acceptor blends and bilayers

Fig. 3

a sEQE spectra for the polymer:m-ITIC 5:1 blends and neat m-ITIC. The curves are shifted to always have the m-ITIC S1 energy (from a bi-Gaussian fit of the sEQE and EL data) at 0 eV for better comparison. At the bottom, a schematic illustration of the driving forces for HT in polymer:m-ITIC 5:1 BHJ samples is shown. b m-ITIC exciton decay (top) and charge rise (bottom) dynamics for polymer:m-ITIC 5:1 BHJ samples, upon selective m-ITIC excitation at 730 nm, obtained from the analysis of the TA data. The y-axis is expressed as a fraction of the total absorbed photon density. Symbols are the experimental data and solid lines are exponential fits obtained globally for the exciton decay and charge rise.

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