Fig. 4: Total synthesis of (+)-caldaphnidine J.
From: Asymmetric total synthesis of yuzurimine-type Daphniphyllum alkaloid (+)-caldaphnidine J

Key transformations were highlighted in colored text. Ac acetyl, AIBN azodiisobutyronitrile, DBU 1,8-diazabicyclo[5.4.0]undec-7-ene, DCE dichloroethane, DDQ 2,3-dichloro-5,6-dicyano-1,4-benzoquinone, DIBAL-H diisobutylaluminium hydride, DMAP 4-dimethylaminopyridine, DME 1,2-dimethoxyethane, dppp 1,3-bis(diphenylphosphino) propane, Naph. naphthalene, TFAA trifluoroacetic anhydride.