Fig. 3: Substrate scopea. | Nature Communications

Fig. 3: Substrate scopea.

From: Catalytic asymmetric C–Si bond activation via torsional strain-promoted Rh-catalyzed aryl-Narasaka acylation

Fig. 3

aReaction conditions: silafluorene 4b (0.20 mmol) and acid anhydrides (0.30 mmol, 1.5 equiv), [Rh(CO)2Cl]2 (0.005 mmol, 2.5 mol%), L7 (0.0125 mmol, 6.25 mol%), and base (30 mol%, Na2CO3 for aliphatic anhydride, Cs2CO3 for aromatic anhydride) in 1,4-dioxane (4.0 mL) at 70 °C for 24 h. bL1 was used as the ligand. cThe reaction time is 48 h.

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