Table 2 Scope with respect to alkyl bromidesa.

From: Migratory functionalization of unactivated alkyl bromides for construction of all-carbon quaternary centers via transposed tert-C-radicals

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  1. aSee the Supplementary Information, pages 27–37, for experimental details. Rr refers to the ratio of desired product to the sum of all the other regioisomers, which was determined by the 19F NMR or GC analysis of the crude products.
  2. bFrom tert-butyl bromide.
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