Fig. 1: Schematics of the experimental set-ups.

a Droplets formed at the tip of a water-filled capillary (hydrophobic or hydrophilic) inside a parallel plate capacitor. b Droplets formed at the tip of an air-filled capillary. c Direct measurement of electrical charges carried by water droplets using a Faraday cup (comprising aluminum sheet) connected to an electrometer. The inset demonstrates the circuit of the electrometer, where C, V0, and A refer to the capacitance, the voltage across the capacitor, and a low current input amplifier, respectively76.