Fig. 1: Metal catalyzed functionalization of homoenolates and their higher homologs.

a Palladium-catalyzed arylations of cyclopropanol derivatives. b Ni-catalyzed doubly stereoconvergent coupling. c Palladium-catalyzed functionalization of γ-C–H’s of carboxylic acid derivatives. d Ni-catalyzed alkylations with N-hydroxyphthalimides (NHPI).