Fig. 2: Scope of tertiary alcohols. | Nature Communications

Fig. 2: Scope of tertiary alcohols.

From: Access to enantioenriched compounds bearing challenging tetrasubstituted stereocenters via kinetic resolution of auxiliary adjacent alcohols

Fig. 2

a Scope of diaryl tertiary alcohols. b Scope of dialkyl tertiary alcohols and triaryl tertiary alcohols. Variations of the standard conditions: 1n: (S)-BTM (10 mol%), rt; 1r: anhydrous Na2SO4 (150 mg), toluene, 0 °C, 11 h; 1x: rt, 20 h; 1y: −40 °C; 1aa–1ad: (S)-BTM (10 mol%), Na2SO4 (150 mg), toluene; 1ad: −20 °C. c conversion.

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