Table 1 Summarized photoelectric properties for the CQD solids prepared under different conditions.

From: The effect of water on colloidal quantum dot solar cells

Deposition Condition

First excitonic peak (meV)

PL peak position (meV)

Stokes shift (meV)

CB (eV)

VB (eV)

Electron mobility

ma(cm2V−1s−1)

Trap state density

ntrapa (cm−3)

PL lifetimeb

t1 (ns)

t2 (ns)

Spin

 Dry air

1369

1146

223

−4.18

−5.57

9.38 × 10−5

1.76 × 1016

2.82

12.49

 Humid air

1372

1067

305

−4.00

−5.42

5.47 × 10−5

3.21 × 1016

0.45

1.83

CA

 Dry air

1356

1187

169

−4.23

−5.62

1.77 × 10−4

1.72 × 1016

3.05

14.50

 Humid air

1359

1170

189

−4.15

−5.54

8.51 × 10−5

2.10 × 1016

2.10

5.84

  1. aThe mobility and trap state density is calculated from the SCLC measurement in Supplementary Fig. 15.
  2. bThe lifetime is fitted from Fig. 3d by a second-order exponential model.