Table 1 Electrolyte compositions for CO2 electrolysis.

From: Efficiency and selectivity of CO2 reduction to CO on gold gas diffusion electrodes in acidic media

Conductivity

cation

Λ+ 10−4·S·m2·mol−1

anion

Λ−104·S·m2·mol−1

H+

349.6

OH

198

Rb+

77.8

SO42−

160

Cs+

77.2

CO32−

138.6

K+

73.4

HPO42−

114

Na+

50.1

Br

78.1

Li+

38.7

I

76.8

  

Cl

76.3

  

NO3

71.4

  

ClO4

67.3

  

F

55.4

  

HCO3

44.5

  

H2PO4

36

Solubility

salt

molal*

salt

molal*

KOH

21.6

K2HPO4

8.6

K2SO4

6.9

KBr

45.0

K2CO3

8.0

KNO3

31.3

KHCO3

2.2

KClO4

0.1

  1. Equivalent ionic conductivity29 (Λ°) of commonly used electrolyte ions, and feasible molality based on the solubility30 of potassium salts containing different anions.
  2. *Molality (mol kg−1) calculated assuming the maximum concentrations feasible according to the solubility values at 20 °C30.