Fig. 5: Development of amino acid and peptide labels.

a Scope of rhodaelectro-catalyzed peptide labeling. b Photoelectrochemical annulation towards π-extended peptide labels. c Absorption and emission properties of 62 (10 mg/L) and 70 (0.5 mg/L) in CHCl3. d Late-stage functionalization of pentapeptide 71. aWith tAmylOH/H2O (3:1). b7 h. cWith 5.0 mol % of [Cp*RhCl2]2. dWith MeOH instead of EtOH.