Fig. 3: Scope of the substrates that undergo migratory allylic substitution.
From: Palladium-catalyzed regio- and enantioselective migratory allylic C(sp3)-H functionalization
The reactions were run with 1 (0.22 mmol), 2 (0.2 mmol), [Pd(allyl)Cl]2 (2.5 mol%), L9 (5 mol%), NaBArF4 (5 mol%) in Et3N (0.2 mL) at 60 oC for 24 h. EWG, electron-withdrawing group. aThe er value was determined by the HPLC analysis of the desilyl derivative of 4a.
