Fig. 5: Mechanistic studies.
From: Palladium-catalyzed regio- and enantioselective migratory allylic C(sp3)-H functionalization
a Control experiments to uncover the reaction intermediates. b Deuterium labeling studies show the involvement of olefin migration. c Crossover experiments. d Kinetic isotope effect. e Rate law determination to elucidate the rate-determining step. f Initial kinetic studies of 3a and 17 for induction period determination.
