Table 1 Representative polymerization data for tunable glycobrushes.
From: Tunable, biodegradable grafting-from glycopolypeptide bottlebrush polymers
Backbone | Brush | Cleaved branches | ||||||
|---|---|---|---|---|---|---|---|---|
Entry | Name | [M] : [I]a | Mnb | Mnb | Ðb | [M] : [I]c | Mnb | Ðb |
1 | PAMK63-g-PGalNAcS33 | 20 | 21.6k | 434k | 1.43 | 20 | 13.7k | 1.28 |
2 | PAMK63-g-PLacS43 | 20 | 21.6k | 565k | 1.40 | 20 | 30.0k | 1.02 |
3 | PAMK63-g-PGlcK17 | 20 | 21.6k | 557kd | ND | 10 | 8.5k | 1.08 |
4 | PAMK63-g-PGlcK23 | 20 | 21.6k | 750kd | ND | 20 | 11.4k | 1.18 |
5 | PAMK63-g-PGlcK117 | 20 | 21.6k | 3686kd | ND | 100 | 58.5k | 1.03 |
6 | PAMK63-g-(PGlcK0.5-s-PBnE0.5)24 | 20 | 21.6k | 566kd | ND | 10 | 8.6k | 1.05 |
7 | PAMK63-g-(PGlcK0.5-s-PBnE0.5)38 | 20 | 21.6k | 884kd | ND | 20 | 13.7k | 1.15 |
8 | PAMK63-g-(PGlcK0.5-s-PBnE0.5)54 | 20 | 21.6k | 1246kd | ND | 50 | 19.4k | 1.28 |
9 | PAMK63-g-(PGlcK0.5-s-BnE0.5)82 | 20 | 21.6k | 1881kd | ND | 100 | 29.5k | 1.22 |
10 | (PAMK0.25-s-PZK0.75)75-g-PGlcK68 | 20 | 21.2k | 661kd | ND | 100 | 34.2k | 1.19 |
11 | (PAMK0.5-s-PEG2K0.5)150-g-PGlcK35 | 50 | 47.3ke | 1729kd,e | ND | 100 | 22.5k | 1.04 |
12 | (PAMK0.5-s-PEG2K0.5)300-g-PGlcK45 | 100 | 94.6ke | 3007kd,e | ND | 100 | 19.5k | 1.09 |
