Fig. 5: The epimerization-glycosylation reactions with large glycosyl donors.
From: Stereoselective gold(I)-catalyzed approach to the synthesis of complex α-glycosyl phosphosaccharides
aYields of α/β mixtures (α/β mixtures were not separable), and α/β ratios were determined by 31P NMR. Bn: benzyl. Bz: benzoyl. In red are the formed glycosidic bonds. In blue are the acceptors of phosphoric acids and the phosphate moieties in the products.
