Table 1 Comparison of the activity of Pd/Py-COF and Pd/Be-COF in the hydrogenation reactionsa.
From: The promotion effect of π-π interactions in Pd NPs catalysed selective hydrogenation
Entry | Substrate | Product | t (h) | Conv. (%) | Sel. (%) | TOF (h-1)b | Ratio of TOFc |
|---|---|---|---|---|---|---|---|
1 |
|
| 3 | >99 | >99 | 275 (50) | 5.5 |
2 |
|
| 10 | >99 | >99 | 92 (15) | 6.1 |
3 |
|
| 1 | >99 | >99 | 641 (195) | 3.3 |
4 |
|
| 3 | >99 | >99 | 277 (50) | 5.6 |
5 |
|
| 2.5 | >99 | >99 | 389 (134) | 2.9 |
6 |
|
| 0.75 | >99 | >99 | 15751 (5529) | 2.9 |
7 |
|
| 1 | 98 | 99 | 24015 (6015) | 4.0 |
8 |
|
| 1 | 52 | >99 | 439 (38) | 11.6 |
