Fig. 7: Photocatalysis by the heterodinuclear complexes. | Nature Communications

Fig. 7: Photocatalysis by the heterodinuclear complexes.

From: Outpacing conventional nicotinamide hydrogenation catalysis by a strongly communicating heterodinuclear photocatalyst

Fig. 7

Temperature dependent photocatalysis of complexes 2 (orange), 4 (red) and 5 (gray). TON as solid dots, TOF as hollow dots (dotted lines guide the eye; error bars represent standard deviation, n = 2 individual measurements for all panels). a Temperature dependent TOF within the first 10 min of photocatalysis and average TOF of 2, 4 and 5 (within 90 min or until substrate limitation) in formate-driven catalysis (blue) for comparison. b TON after 90 min of photocatalysis for the three complexes (acetonitrile/H2O (1/2, v/v), 0.12 M TEA, 0.1 M NaH2PO4, 5 µM catalyst, 250 µM NAD+). c Photocatalysis at 25 °C. d Photocatalysis at 45 °C.

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