Fig. 6: Possible mechanism.

a Proposed mechanism via reductive quenching cycle. b Free energy profiles calculated for the reaction of L4CuII(CN)2 with Int1. Relative free energies are given in kcal/mol.
a Proposed mechanism via reductive quenching cycle. b Free energy profiles calculated for the reaction of L4CuII(CN)2 with Int1. Relative free energies are given in kcal/mol.