Fig. 4: Electrochemical asymmetric allylic N-heteroarylation.
From: Palladium-catalyzed asymmetric allylic 4-pyridinylation via electroreductive substitution reaction
Conditions: 1a (0.2 mmol), 2 (0.6 mmol), PdCl2 (10 mol%), L2 (12 mol%), 5:1 (v/v) MeCN/MeOH, Et4NCl (0.1 M), Zn(+)|GF(-), 8 mA/cm3, 3 h, 35 °C; isolated yields are reported; ee values were determined by HPLC on a chiral stationary phase.
