Fig. 7: Control experiments.
From: Divergent regioselective Heck-type reaction of unactivated alkenes and N-fluoro-sulfonamides
a Crossover experiments. b With external amidyl radical precursor. c Deuterium-labeling experiments. d Radical trapping and radical clock experiments. e Evidence for no isomerization. f Extending to other alkyl electrophiles. TFA trifluoroacetic acid, NFSI N-fluorobenzenesulfonimide, TEMPO 2,2,6,6-tetramethyl-1-piperidinyloxy, BHT butylated hydroxytoluene.
