Table 1 Crystallographic details of Ag5BHT (ref. 19) and CuAgxBHT obtained from the Rietveld refinement using synchrotron PXRD and RED data

From: Construction of conducting bimetallic organic metal chalcogenides via selective metal metathesis and oxidation transformation

 

Ag5BHT

CuAg4BHT

CuAg2BHT

Formula

Ag5C6S6

CuAg4C6S6

CuAg2C6S6

Formula weight

803.77

759.44

543.71

Crystal system

Monoclinic

Monoclinic

Triclinic

Space group

I2/m

P21/c

P−1

a, b, c (Å)

15.1168, 9.1042, 4.2776

4.2773, 8.7547, 14.4847

3.5790, 8.4259, 8.8001

α, β, γ (°)

90, 110.43, 90

90, 94.31, 90

62.09, 86.14, 80.80

V (Å3)

551.67

540.86

231.49

Rwp, Rp

4.98%, 3.45%

4.64%, 3.57%

2.62%, 2.21%

GOF

3.46

1.42

1.31

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