Fig. 2: Substrate scope for the Pd-catalyzed sila-spirocyclization of 1 involving Si–C(sp3) bond cleavage/coupling. | Nature Communications

Fig. 2: Substrate scope for the Pd-catalyzed sila-spirocyclization of 1 involving Si–C(sp3) bond cleavage/coupling.

From: Sila-spirocyclization involving unstrained C(sp3)−Si bond cleavage

Fig. 2

Reactions were carried out by using [Pd]-1 (0.01 mmol), LiOtBu (0.6 mmol), AgOAc (0.4 mmol), CuTc (0.04–0.2 mmol), and 1 (0.2 mmol) in Cyclohexane (0.4 M) or Toluene (0.4 M) for 4–12 h. Isolated yields are shown.

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