Table 3 Summary of the thermodynamic and kinetic parameters of furfural hydrogenation on Pd/C at 0.25–10 bar H2 and room temperature
From: Impact of hydronium ions on the Pd-catalyzed furfural hydrogenation
pH | \({K}_{F}^{o}\)a [\({G}_{F}^{o}\) (kJ mol−1)] | \({K}_{{H}_{2}}^{o}\)b [\({G}_{{H}_{2}}^{o}\) (kJ mol−1)] | \({K}_{1}^{o}\)c [\({G}_{1}^{o}\) (kJ mol−1)] | \({k}_{2}\)(s−1)c |
|---|---|---|---|---|
1.6 | 2297 ± 282 [−19.2 ± 0.3] | 9.03 × 10−2 [5.97] | 10.3 × 10−4 [16.4] | 1322 |
3 | 11.9 × 10−2 [5.27] | 8.52 × 10−4 [17.0] | 1127 | |
5.8 | 18.9 × 10−2 [4.13] | 4.43 × 10−4 [18.5] | 616 | |
7 | 21.5 × 10−2 [3.80] | 2.56 × 10−4 [19.8] | 357 |
