Fig. 1: Synopsis for Ni-catalyzed hydroarylation and hydroalkenylation of internal alkenes.

a Transition-metal catalyzed hydroarylation of alkenes. b Ni-catalyzed hydroarylation of internal alkenes with arylborons. c Ligand enabled Ni-catalyzed hydroarylation and hydroalkenylation of internal alkenes with organoborons. Ar aryl, PMP p-methoxyphenyl.