Fig. 2: Ligand evaluation for Ni-catalyzed hydroarylation of internal alkenes. | Nature Communications

Fig. 2: Ligand evaluation for Ni-catalyzed hydroarylation of internal alkenes.

From: Ligand-enabled Ni-catalyzed hydroarylation and hydroalkenylation of internal alkenes with organoborons

Fig. 2

Reaction conditions: 1 (0.1 mmol, 1.0 equiv), 2a (0.2 mmol, 2.0 equiv), Ni(OTf)2 (10 mol%), Ligand (10 mol%), Na3PO4 (32.8 mg, 2.0 equiv), t-AmylOH (0.5 mL), 80 °C, N2, 10 h; Ad 1-adamantyl, ND not detected. The yield was determined by 1H NMR using dibromomethane as the internal standard.

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