Table 3 Catalytic syngas conversion over Mo3S4@NaZSM-5 and Mo3S4@HZSM-5

From: COx hydrogenation to methanol and other hydrocarbons under mild conditions with Mo3S4@ZSM-5

Feed gas

Catalyst

Conversion (%)a

Selectivity (%)

CH3OH

CH4 /C2-C3b

CO2

2CO/H2

Mo3S4@NaZSM-5

2.6

97.6

2.4/–

0.8

Mo3S4@HZSM-5

3.2

–

2/98

45

CO/2H2

Mo3S4@NaZSM-5

5.4

81

19/–

7.6

Mo3S4@HZSM-5

5.8

–

25/75

39

  1. Reaction conditions: 260 °C, 4 MPa, 4,000 mL gcat-1 h-1 of GHSV.
  2. aSingle-pass conversion of CO.
  3. bC2 -C3 hydrocarbons (including olefins and alkanes) selectivity in organic products. Calculation methods are given in Methods section.
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