Table 1 Summarized material characterization data

From: Hybridization of short-range and long-range charge transfer excited states in multiple resonance emitter

 

HOMOa

(eV)

LUMOa

(eV)

λabsb

(nm)

λemc

(nm)

ESc

(eV)

ETc

(eV)

ΔESTc

(eV)

Stokes Shift

(nm)

FWHM

(nm)

2,5-tDPAtDIDCz

−5.55

−2.74

429

438

2.83

2.65

0.18

32

32

1,6-tDPAtDIDCz

−5.54

−2.66

411

415

2.99

2.58

0.41

25

29

  1. ameasured by oxdiation and reduction method using 0.1 M of tetrabutylammonium perchlorate in acetonitrile solution with ferrocene and mCP as a reference material. bmeasured at room temperature with 10−5 M of THF solution. cmeasured at 77 K in frozen THF matrix without and with 1.0 millisecond delay.
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