Fig. 7: Applications of the radical sulfonylation reaction. | Nature Communications

Fig. 7: Applications of the radical sulfonylation reaction.

From: Turning sulfonyl and sulfonimidoyl fluoride electrophiles into sulfur(VI) radicals for alkene ligation

Fig. 7

a Competition reaction between the radical and nucleophilic substitution. b Gram-scale synthesis and post-modification. (Reaction conditions: atrimethylsulfoxonium iodide, NaOH, rt. btris(trimethylsilyl)-silane, AIBN, reflux. cethyl isocyanoacetate, NaOH, rt. dDPPO, KOH, O2, rt. ebenzyl mercaptan, Et3N, rt. fpyrrolidine, rt. gdimethyl malonate, triton-B, 70 oC. hcyclopentanone, triton-B, 70 oC. in-butylamine, 70 oC). c Divinyl sulfone as dyes. d New polymer synthesis.

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