Fig. 4: ICT effect between GDY and R6G. | Nature Communications

Fig. 4: ICT effect between GDY and R6G.

From: Surfactant-free interfacial growth of graphdiyne hollow microspheres and the mechanistic origin of their SERS activity

Fig. 4

a The Tauc plot curve shows a direct optical bandgap at 1.71 eV for GDY HHMSs. b Band energy alignment diagram of the charge-transfer pathways in GDY HHMSs. ICT: interfacial charge transfer, GSCT: ground-state charge transfer resonance. c Absorption spectra of pristine R6G solution (5 mg L−1) and R6G solution (5 mg L−1) mixed with GDY HHMSs (10 mg L−1) and graphene nanosheets (10 mg L−1). The inset shows the colour of the respective solutions. d Photoluminescence spectra of pristine R6G solution (5 mg L−1) and R6G solution (5 mg L−1) mixed with GDY HHMSs (10 mg L−1) and graphene nanosheets (10 mg L−1). Source data are provided as a Source Data file.

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