Fig. 3: Electrochemical investigation. | Nature Communications

Fig. 3: Electrochemical investigation.

From: Challenging an old paradigm by demonstrating transition metal-like chemistry at a neutral nonmetal center

Fig. 3

a Overlay of cyclic voltammograms of 3b, 3c, 3cCr and 3d at a Pt electrode in a 0.2 M nBu4PF6/THF solution; analyte concentration of 0.5 mM (3b) and 1.0 mM (3c, 3cCr, 3d) oxidation parts with anodic scan direction and reduction parts with cathodic initial scan direction as denoted with arrows; scan rate: 200 mV s−1; potentials are referenced versus Fc+/0. b Plots of the Kohn-Sham HOMO and LUMO of complexes 3c and 3d’.

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