Table 1 CTH of various aldehydes over Fe-ZIF-8-800 catalyst.a
From: Highly active, ultra-low loading single-atom iron catalysts for catalytic transfer hydrogenation
Entry | Aldehyde substrate | T [°C] | t [h] | Conv. [%] | Product | Yield [%]b | Sel. [%] |
|---|---|---|---|---|---|---|---|
1 |
| 80 120 | 3 1 | 96.6 99.5 |
| 90.1 93.1 | 93.3 93.5 |
2 |
| 120 | 6 | 20.1 |
| 13.6 | 67.7 |
3 |
| 120 | 6 | 100 |
| 79.3 | 79.3 |
4 |
| 120 | 6 | 44.4 |
| 35.5 | 79.9 |
5 |
| 120 | 6 | 18.7 |
| 0.8 | 4.2 |
6 |
| 120 | 6 | 21.8 |
| 11.0 | 50.5 |
7 |
| 120 | 6 | 99.8 |
| 93.5 | 93.7 |
8 |
| 120 160 | 6 0.5 | 100 100 |
| 89.5 91.4 | 89.5 91.4 |
9 |
| 120 160 | 6 6 | 36.9 99.8 |
| 27.6 64.7 | 74.8 64.8 |
10 |
| 120 | 6 | 97.9 |
| 88.0 | 89.9 |
11 |
| 160 | 6 | 25.9 |
| 22.1 | 85.3 |
12 |
| 140 160 | 6 6 | 55.7 87.5 |
| 13.9 17.0 | 25.0 19.4 |
13 |
| 140 160 | 6 6 | 52.1 85.5 |
| 39.1 62.4 | 75.0 73.0 |
14 |
| 120 160 | 6 1 | 97.9 100 |
| 88.0 87.7 | 89.9 87.7 |
15 |
| 160 | 6 | 90.5 |
| 69.2 | 76.5 |
