Fig. 2: Preparation of the NHSi-stabilized ditin(0) complex (2). | Nature Communications

Fig. 2: Preparation of the NHSi-stabilized ditin(0) complex (2).

From: A silylene-stabilized ditin(0) complex and its conversion to methylditin cation and distannavinylidene

Fig. 2

The reaction of 1 with 1 equivalent of Jones’ magnesium(I)-reducing agent in toluene affording ditin (0) complex (2). The reaction of 1 with 0.5 equivalent of Jones’ magnesium(I)-reducing agent in toluene affording ditin(I) bromide (3). The reaction of 3 with 2 equivalents of KHBBus3 in THF affording ditin (0) complex (2).

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