Table 1 Summary of photoisomerization rate constants for spiropyran, hydrazone, and diarylethene derivatives in solution and coordinatively-integrated in frameworks

1^a

EtOH

0.033(5)

6^b

DMF

0.015(5)

1^a

toluene

0.060(7)

UiO-67 + 6

DMF

0.029(3)

1^a

THF

0.074(4)

UiO-67 + 6

solvent-free

0.026(2)

1^a

DMF

0.14(2)

7^b

MeOH

0.00060(7)

2^a

DMF

0.036(2)

8^b

MeOH

0.00060(8)

2^a

THF

0.048(4)

9^b

toluene

0.03(1)

UiO-67 + 2

DMF

0.061(4)

10

solid state

0.13(3)

UiO-67 + 2

solvent-free

31.2(5)

11

solid state

0.0337(5)

3^a

EtOH

0.037(3)

11^c

DMF

0.19(1)

3^a

toluene

0.07(2)

UiO-67 + 11

DMF

0.32(2)

3^a

DMF

0.08(1)

UiO-67 + 11

solvent-free

0.177(3)

3^a

CH₃CN

0.054(4)

12

solid state

0.36(6)

Zn₂(3)(DBTD)

DMF

0.054(7)

12^c

DMF

0.037(3)

Zn₂(3)(DBTD)

solvent-free

53(2)

12^c

EtOH

0.005(1)

4^b

toluene

0.0086(3)

12^c

toluene

0.009(1)

4^b

DMF

0.0074(3)

Zn₂(12)(DBTD)

DMF

0.0033(3)

5^b

DMF

0.00484(1)

13^c

CH₃CN

0.010(6)

5^b

EtOH

0.016(3)

UiO-67 + 2 + 5

DMF

0.084(3)^d0.0004(1)^e

UiO-67 + 5

DMF

0.005(2)

UiO-67 + 2 + 5

solvent-free

55(2)^d 0.00097(3)^e

UiO-67 + 5

solvent-free

0.013(4)