Fig. 1: Background and concept. | Nature Communications

Fig. 1: Background and concept.

From: Catalyst control over pentavalent stereocentres

Fig. 1

a Selected pentavalent phosphoranes. b Pentavalent stereocentres. c Fourfold stereogenicity in pentavalent stereocentres. d Stereoisomerisation of pentavalent dioxophosphoranes32,33,34,35,36,37. e Auxiliary (Xc*) approaches & dehydrogenation of hydridophosphoranes. f Recent strategies to catalytically control tetravalent phosphorus stereocentres. g Catalyst control over pentavalent phosphorus stereocentres (this work).

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