Fig. 3: Scope of the method.
Conditions: hydridophosphorane substrate 1a-p (100 μmol), catalyst C8 (5.00 μmol), 5.0 mL toluene, 0 °C, 20 h. Yields are given for isolated products. The d.r. was determined as (trans):(cis) by 19F NMR of the crude reaction mixture and the e.r. as (S):(R) by HPLC on a chiral stationary phase of the isolated product.
