Table 3 Summary of structures and lifetime measurements of blue OLED devices A to L where the base host material mCBP is 3,3′-Di(9H-carbazol-9-yl)−1,1′-biphenyl, DBFPO is 2,8-bis(diphenylphosphineoxide)-dibenzofuran, TSPO1 is diphenyl[4-(triphenylsilyl)phenyl]phosphine oxide, Liq is lithium quinolinate, ν-DABNA is N7,N7,N13,N13,5,9,11,15-octaphenyl-5,9,11,15-tetrahydro-5,9,11,15-tetraaza-19b, 20b-diboradinaphtho[3,2,1-de:1′,2′,3′-jk] pentacene-7,13-diamine

From: Direct identification of interfacial degradation in blue OLEDs using nanoscale chemical depth profiling

#

Device type

EML

HBL

ETL

LT90 (h)

LT70 (h)

LT50 (h)

A

Phosphorescent with DBFPO

mCBP (Host 1):Ir (Dopant 1)

DBFPO

DBFPO:Liq

0.2

0.7

1.37

B

TADF with TSPO1

mCBP (Host 1):ν-DABNA (Dopant 2) 5%

TSPO1

TSPO1:Liq

0.2

0.4

0.5

C

Phosphorescent with DBFPO

mCBP-CN (Host 2):Ir (Dopant 1)

DBFPO

DBFPO:Liq

2.8

17.5

52.6

D

TADF with TSPO1

mCBP-CN (Host 2):ν-DABNA (Dopant 2) 5%

TSPO1

TSPO1:Liq

0.3

2

6.8

E

Phosphorescent with DBFPO

mCBP-(CN)2 (Host 3):Ir (Dopant 1)

DBFPO

DBFPO:Liq

5.4

29.3

80.3

F

TADF with TSPO1

mCBP-(CN)2 (Host 3):ν-DABNA (Dopant 2) 5%

TSPO1

TSPO1:Liq

0.8

3.8

10.5

  1. The molecular structure of the Ir dopants is given in Supplementary Table 1.