Fig. 2: Long-term stability of the p–n OED.

a An illustration of the p–n OED sealing with a top layer of p(g2T-TT) and SU-8. The blue arrow shows the diffusion barrier for cations between the OED and the overlying electrolyte. The white arrow indicates the p–n OED channel. b p–n OED operation as a half-wave rectifier. The green curve represents the sinusoidal input applied between the anode and cathode electrodes, and the orange curve is the output current of the p–n OED. (n = 20 repetitions per device. n = 5 devices.) c p–n OED operational stability performance without top sealing (in green) and with top sealing (in orange) during the application of 200-Hz cathodic pulses. The peak values of \({I}_{C}\) response is fitted with an exponential decay function (blue line). The corresponding device schematic is placed at the inset of each graph to illustrate the p–n OED architecture used. d Long-term performance of the sealed p–n OEDs during the application for 0.8-V biphasic pulses. Pulses shown in green (10 pulses at 10 Hz) are acquired after continuous application of 1000 pulses. Pulses shown in orange are acquired after p–n OED is recharged through a new cation injection.