Fig. 6: 3D-ED structure of Pd3-MOF.
Single-crystal 3D-ED structure of Pd3-MOF showing the asymmetric unit (50% thermal ellipsoids, C (black), N (pale blue), Pd (dark blue); a) and views of an extended two-dimensional sheet perpendicular (b) and parallel (c) to the mean plane through the sheet. H atoms are omitted for clarity. Selected bond lengths and angles: Pd–Pd: 2.66–2.73 Å; Pd–Cterminal: 1.75-2.01 Å; Pd–Cbridging: 2.02–2.20 Å; N–Cterminal: 1.15–1.23 Å; N–Cbridging: 1.18–1.25 Å; Pd–Pd′–Pd″: 59–62°; Cterminal–N–Ar: 172–173°; Cbridging–N–Ar: 130, 134, 170°.
