Fig. 8: The DFT studies of R-AuL6 + S-CaA* model. | Nature Communications

Fig. 8: The DFT studies of R-AuL6 + S-CaA* model.

From: Diastereo-divergent synthesis of chiral hindered ethers via a synergistic calcium(II)/gold(I) catalyzed cascade hydration/1,4-addition reaction

Fig. 8

This figure depicts reaction paths in (R)-L6[(NCMe)AuSbF6]2 catalytic system. TS1 means transition state 1. INT1 means intermediate 1. TS2A-S, TS2A-R, TS2B-S and TS2B-R means transition state 2 in two model with different absolute configurations. INT2A-R, INT2A-S, INT2B-R and INT2B-S means intermediate 2 in two model with different absolute configurations. TS3A-RR, TS3B-SR, TS3B-RR, TS3A-SS and TS3A-SR means transition state 3 in two model with different absolute configurations. INT3A-RR, INT3B-SR, INT3B-RR, INT3A-SS and INT3A-SR means intermediate 3 in two model with different absolute configurations.

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