Fig. 3: Substrate Scope of monoborylation reaction.
From: Dinuclear gold-catalyzed divergent dechlorinative radical borylation of gem-dichloroalkanes
Reaction conditions: PC1 (3 mol%), gem-dichloroalkanes 1 (0.2 mmol), B2cat2 2 (4 equiv.), DEF (2 mL), blue LEDs, ambient temperature, 24 h; then pinacol (4 equiv.), Et3N (0.5 mL),1 h. a39 (0.2 mmol), DEA (1.1 equiv.), ether, rt, ∼30 min followed by 0.1 M HCl (30 min).
