Fig. 2: Survey of the aryl bromides. | Nature Communications

Fig. 2: Survey of the aryl bromides.

From: Rapid and scalable photocatalytic C(sp2)–C(sp3) Suzuki−Miyaura cross-coupling of aryl bromides with alkyl boranes

Fig. 2

Conditions: 4CzIPN (5 mol%), NiCl2·glyme (10 mol%), dtbbpy (10 mol%), 2,6-lutidine (2.0 equiv.), 1a (1.0 equiv.) and 2 (0.5 mmol) in CH3CN (0.1 M). The solution was N2-bubbled and subsequently irradiated with a blue LED (λ = 456 nm) for 3 h (see Section 1.5 in Supplementary Information). Yields are meant after isolation, unless otherwise stated. a NMR yield is given because of the volatility of the compound.

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