Fig. 2: Development of asymmetric skeletal reorganization reaction.
From: Organocatalytic skeletal reorganization for enantioselective synthesis of S-stereogenic sulfinamides
a Preliminary experiments. b Control experiments. rac-P0 = Me2P+Ph2I-. Reactions were conducted by using different N-protected sulfoximines (0.1 mmol) in the presence of racemic catalyst P0/P2 (20 mol%), KOH (2.0 equiv.) in toluene (2.5 ml) at r.t. The isolated yields were given.
