Table 2 Enantioselective anodic oxidative allylation reactions

From: Enantioselective nickel-catalyzed anodic oxidative dienylation and allylation reactions

  1. Unless otherwise specified, all reactions were carried out using racemic benzoxazolyl acetate 1 (0.1 mmol), allylic counterpart 7 (0.30 mmol), nBu4NPF6 (0.15 mmol), quinuclidine (0.05 mmol), Ni(OAc)2·4H2O (10 mol%), L9 (10 mol%), Cp2Fe (10 mol%), and DCM/TFE/MeOH = 3:2:1 (3 mL) at 25 °C for 3 h under constant-current conditions in an undivided cell. a0.5 mmol scale. bHCO2H (20 mol%). c6 h. dPotassium allyltrifluoroborate (0.30 mmol, 3.0 equiv) and HCO2H (10 mol%) were used, 25 °C, 6 h. e10 °C. fWith 7 (0.6 mmol) at 50 °C.
Back to article page